Auxiliaries for Dyeing
The following are some of the auxiliary agents commonly used by companies in their processes:
Hydrotropic and solubilization color agents are used to dissolve large amounts of color in a small amount of water. These agents increase the solubility due to their amphoteric properties and are employed in the techniques of Pad Batch or Pad Steam.
Some solvents are used in dyeing and printing to rinse color residues from the devices and equipment used in the process. Also, some auxiliaries used in continuous dyeing contain solvents, hydrotropic agents and surfactants, not only for their ability to solubilize the dye, but also to improve the color-fixing process.
Commercial products offered to dissolve color contain mixtures of solvents, dispersants and surfactants. Solvents and hydrotropic agents are needed when fabric is dyed with certain types of colors.
Protective Agents for Reducing Heat
Under unfavorable conditions, some colors may change their molecular structure during processing. In these cases, special color protection agents are added to dye baths to prevent heat reduction of the dye. It is also very important to maintain precise control of pH, which is achieved by adding a buffer solution and oxidizing agents.
Wetting Agents
The fundamental prerequisite for proper dyeing in an aqueous bath is a complete soaking of the fabric. This is accomplished by means of wetting agents, whose use depends on the dyeing process in question and the nature and condition of the material to be dyed.
Dispersants and Protective Colloids
Dyes insoluble in aqueous dispersions are used in various processes of dyeing and printing. Dispersants are needed to prepare these dyes to stabilize their dispersed state with precision during application. Dispersants can also prevent precipitation of the dyes.
The dispersants used can be divided into two classes:
a) surfactants
b) Mono- and poly-electrolytes soluble in water
Both have an amphoteric structure, and their function is based on the formation of electrostatic and mechanical protective films around the dispersed particles of the dye, thus preventing precipitation and agglomeration.
Complex Agents
Water quality is of great importance to the steps in the dyeing process, where insoluble impurities and salts from heavy metals can cause considerable problems, including:
a) The formation of sparingly soluble compounds with anionic color salts, causing problems of dispersion, filtering, and color imbalances, among others.
b) The formation of stable complexes with dye molecules, causing changes in the tone accompanied by the loss of color intensity.
Therefore, purifiers and softeners are added to the dye bath to trap the multivalent ions, especially calcium and magnesium ions and iron salts, preventing them from interfering with the dyeing process.
Leveling Agents
Leveling agents facilitate the uniform distribution of dyes in the fabric in order to obtain tones and intensities of uniform color. These agents act by reducing the overall speed of the dyeing process, while increasing the speed of the migration of the dye into the fabric and increasing the solubility or stability of the color dispersed during dyeing. These agents are used in processes of dyeing by depletion.
Inequalities in color are caused or exacerbated by the following factors:
a) Variable affinity of the color to the fibers
b) Variable affinity of the fibers to the color
c) Inadequate distribution of fluid in the textile
d) Differences in temperature in the textile
These inequalities can be prevented by optimizing the dyeing techniques (for example, improving the diffusion of fluid into the textile and controlling the pH) using leveling agents.